Sales email template file: app/locale/en_US/template/email/sales/order_new.html.
Sample workout :
{{template config_path="design/email/header"}}
{{inlinecss file="email-inline.css"}}
<table cellpadding="0" cellspacing="0" border="0">
<tr>
<td>
<table cellpadding="0" cellspacing="0" border="0">
<tr>
<td class="email-heading">
<?php
$website_id = Mage::app()->getWebsite()->getId();
if($website_id == "2") : ?>
<h1>Welcome you for your order from {{var store.getFrontendName()}}.</h1>
<?php else : ?>
<h1>Thank you for your order from {{var store.getFrontendName()}}.</h1>
<?php endif; ?>
<p>Once your package ships we will send an email with a link to track your order. Your order summary is below. Thank you again for your business.</p>
</td>
<td class="store-info">
<h4>Order Questions?</h4>
<p>
{{depend store_phone}}
<b>Call Us:</b>
<a href="tel:{{var phone}}">{{var store_phone}}</a><br>
{{/depend}}
{{depend store_hours}}
<span class="no-link">{{var store_hours}}</span><br>
{{/depend}}
{{depend store_email}}
<b>Email:</b> <a href="mail to:{{var store_email}}">{{var store_email}}</a>
{{/depend}}
</p>
</td>
</tr>
</table>
</td>
</tr>
<tr>
<td class="order-details">
<h3>Your order <span class="no-link">#{{var order.increment_id}}</span></h3>
<p>Placed on {{var order.getCreatedAtFormated('long')}}</p>
</td>
</tr>
<tr class="order-information">
<td>
{{if order.getEmailCustomerNote()}}
<table cellspacing="0" cellpadding="0" class="message-container">
<tr>
<td>{{var order.getEmailCustomerNote()}}</td>
</tr>
</table>
{{/if}}
{{layout handle="sales_email_order_items" order=$order}}
<table cellpadding="0" cellspacing="0" border="0">
<tr>
<td class="address-details">
<h6>Bill to:</h6>
<p><span class="no-link">{{var order.getBillingAddress().format('html')}}</span></p>
</td>
{{depend order.getIsNotVirtual()}}
<td class="address-details">
<h6>Ship to:</h6>
<p><span class="no-link">{{var order.getShippingAddress().format('html')}}</span></p>
</td>
{{/depend}}
</tr>
<tr>
{{depend order.getIsNotVirtual()}}
<td class="method-info">
<h6>Shipping method:</h6>
<p>{{var order.shipping_description}}</p>
</td>
{{/depend}}
<td class="method-info">
<h6>Payment method:</h6>
{{var payment_html}}
</td>
</tr>
</table>
</td>
</tr>
</table>
{{template config_path="design/email/footer"}}
I just want to add if-else condition like, inside the class(<td class="email-heading">)
<td class="email-heading">
<?php
$website_id = Mage::app()->getWebsite()->getId();
if($website_id == "2") : ?>
<h1>Welcome you for your order from {{var store.getFrontendName()}}.</h1>
<?php else : ?>
<h1>Thank you for your order from {{var store.getFrontendName()}}.</h1>
<?php endif; ?>
<p>Once your package ships we will send an email with a link to track your order. Your order summary is below. Thank you again for your business.</p>
</td>Any help thank.